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Influence of Hydrogen Concentration on TiO_2 Nanoparticles Prepared by Gaseous Detonation

机译:氢浓度对气相爆轰法制备TiO_2纳米粒子的影响

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This article is mainly introduced the detonation method to prepare TiO_2 nanoparticles which use hydrogen-oxygen gas mixture as the explosion source and the titanium tetrachloride as the precursor. It studied TiO_2 nanoparticles influenced by different hydrogen concertration. And analyzed the character of prepared TiO_2 nanoparticles by XRD and TEM. The results show that the powders are mixed crystal of Rutile and Anatase. It is also found that the relative content of rutile grows larger and the size of grain becomes smaller (about 30~100nm) as the hydrogen content increases, and the TiO_2 nanoparticles are mostly spherical. But the dispersion is becomes slightly worse, and the agglomeration appear.
机译:本文主要介绍了以氢氧混合气为爆炸源,以四氯化钛为前驱体的爆轰制备TiO_2纳米粒子的方法。研究了不同氢原子配比对TiO_2纳米粒子的影响。并用XRD和TEM分析了制备的TiO_2纳米粒子的特性。结果表明,该粉末为金红石和锐钛矿的混合晶体。还发现随着氢含量的增加,金红石的相对含量变大,晶粒尺寸变小(约30〜100nm),并且TiO_2纳米粒子大多为球形。但是分散性会稍微变差,并且会出现团聚。

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