Application of Sharp Analysis on Reduction Kinetics of Vanadium Titanium Magnetite Sintering Ore

摘要

The isothermal reduction kinetics of vanadium titanium magnetite sintering ore was investigated by thermo-gravimetric analysis at a temperature range of 1123-1223 K under 30% CO + 70% N_2 gas mixtures. The apparent activation energy of reduction was calculated by iso-conversional method and its value is 36.7 kJ/mol. The model function describing the reduction mechanism was discussed by Sharp analysis and the results revealed that the reduction process is controlled first by random nucleation and nucleus growth mechanism (RNNGM) as reduction degree is lower than 0.5, followed by the mixed influence of RNNGM and phase boundary reaction when reduction degree is higher than 0.5.