INFLUECE OF BLEND COMPOSITION ON STRUCTURE DEVELOPMENT DURING UNIAXIAL STRETCHING OF MELT MISCIBLE PVC/PCL FILMS

摘要

Polymer blends are increasingly replacing homopolymers, because they synergistically combine the properties of the parent's polymers. In order to improve its processability, PVC is often mixed with plasticizers or blended with other polymers. In this study we investigate the effect of blend composition on the development of orientation, crystallization, and relaxation mechanism that occurs during the uniaxial stretching of miscible PVC/PCL blends studied by real time birefringence measurements system. By varying the blend composition we obtained two sets of materials one amorphous and the other crystalline blends. Stress optical behavior at large deformation from these from these precursors were determined.