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Odorous VOC removal by TiO TiO2 photocatalysts underUV and visible light

机译:紫外线和可见光下TiO TiO2光催化剂去除恶臭的VOC

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摘要

There are many odorous volatile organic compounds (VOCs) presented in indoor andrnoutdoor air near pollutant sources. Several technologies to remove the VOCs andrnreduce odor are available, of which the photocatalytic method has the advantages ofrnlow temperature operation as well as renewable capacity. The most famousrnphotocatalysts are the TiO2 based particles or films. They are capable of removingrnvarious kinds of odorous materials with the assistance of natural sunlight or artificialrnlight sources within the UV light range. Recently the TiO2 based photocatalystsrnhave been modified to be able to utilize a visible light source.rnThis study intends to produce TiO TiO2 based photocatalysts with the plasma assistedrnmethod. The N2 carrier gas is dissociated into N atoms in the plasma environmentrnand then doped into the photocatalyst for purposes of utilizing visible light sources.rnThe TiO2 based photocatalysts were tested to evaluate performance on removing therntoluene and isopropanol (IPA). The removal of both IPA and toluene with thernN-doped TiO2 was demonstrated to be better than pure anatase TiO TiO2 photocatalysts.rnResults of the batch reactor tests showed that near complete removals of IPA underrnboth UV (with 20 min. at 10W) and visible light (within 60 min. at 10W) sourcesrnwere achieved with the N-doped TiO2 photocatalysts. The results demonstrate thatrnthe N-doped TiO2 photocatalyst has a high potential application in the indoor/outdoorrnair pollution control.
机译:室内和室外空气中靠近污染物源的地方存在许多有气味的挥发性有机化合物(VOC)。现有几种去除VOC和减少气味的技术,其中光催化方法具有低温操作和可再生能力的优点。最著名的光催化剂是基于TiO2的颗粒或薄膜。它们能够在紫外线范围内的自然阳光或人造光源的帮助下去除各种气味的材料。最近,对基于TiO2的光催化剂进行了改良,使其能够利用可见光源。本研究旨在利用等离子辅助方法生产TiO2 TiO2基光催化剂。 N 2载气在等离子体环境中分解成N原子,然后掺杂到光催化剂中以利用可见光源。rn测试了TiO2基光催化剂以评估其去除甲苯和异丙醇(IPA)的性能。 N掺杂的TiO2去除IPA和甲苯的效果均优于纯锐钛矿型TiO TiO2光催化剂。间歇反应器测试的结果表明,在紫外线(10W下20分钟)和可见光下,IPA几乎全部去除。 (在10W下60分钟之内)使用N掺杂的TiO2光催化剂实现了光源。结果表明,N掺杂TiO2光催化剂在室内/室外空气污染控制中具有很高的应用潜力。

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