首页> 外文会议>12th Romanian International Conference on Chemistry and Chemical Engineering Sep 13-15, 2001 Bucharest, Romania >The Conformation of Amino and Ammonium Substituted Tricarbonyl-Chromium-Complexes Derived from ~1H- and ~(13)C-NMR Spectra
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The Conformation of Amino and Ammonium Substituted Tricarbonyl-Chromium-Complexes Derived from ~1H- and ~(13)C-NMR Spectra

机译:由〜1H-和〜(13)C-NMR光谱衍生的氨基和铵取代的三羰基-铬络合物的构象

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摘要

NMR data for amino and ammonium substituted arene-chromium-tricarbonyl complexes are presented. The preferential conformation of the chromium tricarbonyl tripod is deduced from NMR data. Substituent increments are calculated and allow the calculation of chemical shifts for polysubstituted amines and ammonium salts, both for free ligands and chromium-tricarbonyl complexes.
机译:给出了氨基和铵取代的芳烃-铬-三羰基配合物的NMR数据。从NMR数据推导出三羰基铬三脚架的优先构象。计算取代基的增量,并允许计算自由取代的配体和三羰基铬络合物的多取代胺和铵盐的化学位移。

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