首页> 外国专利> PROCESSES FOR PREPARING 5,5-DIMETHYL-2-OXO-3-CYCLOPENTENE-1-CARBOXYLATE COMPOUNDS AND 3,5,5-TRIMETHYL-2-OXO-3-CYCLOPENTENE-1-CARBOXYLATE COMPOUNDS FROM 3,3-DIMETHYL-1-BUTENE-1,4-DICARBOXYLATE COMPOUNDS AND 1,3,3-TRIMETHYL-1-BUTENE-1,4-DICARBOXYLATE COMPOUNDS, AND 1,3,3-TRIMETHYL-1-BUTENE-1,4-DICARBOXYLATE COMPOUNDS

PROCESSES FOR PREPARING 5,5-DIMETHYL-2-OXO-3-CYCLOPENTENE-1-CARBOXYLATE COMPOUNDS AND 3,5,5-TRIMETHYL-2-OXO-3-CYCLOPENTENE-1-CARBOXYLATE COMPOUNDS FROM 3,3-DIMETHYL-1-BUTENE-1,4-DICARBOXYLATE COMPOUNDS AND 1,3,3-TRIMETHYL-1-BUTENE-1,4-DICARBOXYLATE COMPOUNDS, AND 1,3,3-TRIMETHYL-1-BUTENE-1,4-DICARBOXYLATE COMPOUNDS

机译:制备5,5-二甲基-2-氧代-3-环戊烯-1-羧酸丁酯化合物的方法和3,5,5-三甲基-2-氧代-3-环戊烯-1-羧酸烯化合物,来自3,3-二甲基-1 - - 丁烯-1,4-二羧酸酯化合物和1,3,3-三甲基-1-丁烯-1,4-二羧酸甲酯化合物,以及1,3,3-三甲基-1-丁烯-1,4-二羧酸酯化合物

摘要

The present invention provides a process for preparing a compound of the following general formula (2): wherein R1 represents a monovalent hydrocarbon group having 1 to 10 carbon atoms, and R3 represents a hydrogen atom or a methyl group, the process comprising: subjecting a compound of the following general formula (1): wherein R1 and R2 represent, independently of each other, a monovalent hydrocarbon group having 1 to 10 carbon atoms, R3 represents a hydrogen atom or a methyl group, and the wavy bond represents an E-configuration, a Z-configuration, or a mixture thereof, to a Dieckmann condensation in the presence of base to form the compound (2).
机译:本发明提供了制备以下通式(2)的化合物的方法:其中R 1代表具有1至10个碳原子的一价烃基,R 3表示氢原子或甲基,该方法包括:受试者 以下通式(1)的化合物:其中R1和R2独立于彼此代表具有1至10个碳原子的一价烃基,R3代表氢原子或甲基,并且波浪键代表E- 在碱存在下,构造,Z-配置或其混合物,在碱存在下粘附以形成化合物(2)。

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