NEW MATERIAL:A compound expressed by formula I {Rf represents perfluoroalkenyl expressed by formula II [R1-R3 represent perfluoroalkyl expressed by CnH2n-1 (n is 1-3)]}. EXAMPLE:Glycidyl para-(perfluorononenyloxy)benzoate. USE:A surfactant, lubricant, cosmetics and high polymer modifier. PREPARATION:A para-(perfluoroalkenyloxy)benzoyl halide expressed by formula III (X represents halogen atom) is reacted with a glycidol in the presence of a basic compound (example; triethylamine or potassium carbonate) normally in the presence of a solvent. As for the solvent, acetone is preferably used when the basic compound is an organic base and DMF, etc., is preferred when the basic compound is an inorganic base.
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机译:新材料:式I表示的化合物{R f表示式II表示的全氟烯基[R 1 -R 3表示C n H 2n-1(n为1-3)表示的全氟烷基]}。实施例:对-(全氟壬烯氧基)苯甲酸缩水甘油酯。用途:表面活性剂,润滑剂,化妆品和高聚物改性剂。制备:在碱性化合物(例如;三乙胺或碳酸钾)的存在下,通常在溶剂的存在下,使由式III(X表示卤素原子)表示的对-(全氟烯氧基)苯甲酰卤与缩水甘油反应。至于溶剂,当碱性化合物为有机碱时优选使用丙酮,而当碱性化合物为无机碱时优选使用DMF等。
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