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Hydrotalcite derivatives comprising nickel and cobalt and a leaf morphology, and method of production.

机译:包含镍和钴的水滑石衍生物以及叶片形态及其生产方法。

摘要

A hydrotalcite synthetic material containing nickel (or cobalt), with laminar morphology, and a relationship between the width and film thickness of at least 50, of the formula M {SUB, 1-X} AL {SUB, X} (OH) {SUB, SUB 2} .XA.MH {2} O, where M is Ni or Co, A is an anion monocarboxylic FORM RCOO-, where R is C {SUB, SUB {N} H , 2N + 1}, n = 0-5, YXYM are numbers that satisfy the following conditions: 0.2 = X = 0.4, 0.0 = M = 4. It is prepared from a synthesis mixture having a molar RATIO Ni or Co (divalent cation) to aluminum (CATION trivalent) between 1: 1 and 10: 1, a mole ratio anion monocarboxylic A ALUMINUM (CATION trivalent) BETWEEN 0.1 : 1 and 1.2: 1 and optionally other additives anions. The process comprises reacting a mixture comprising NI (or cobalt), aluminum cations, and anions monocarboxylic IN A slurry, to less 40 CY a pH of at least 7 TEMPERATURE AL.
机译:一种水滑石合成材料,其具有层状形态的镍(或钴),且宽度与膜厚之间的关系至少为50,分子式为M {SUB,1-X} AL {SUB,X}(OH){ SUB,SUB 2} .XA.MH {2} O,其中M为Ni或Co,A为阴离子一元羧酸FORM RCOO-,其中R为C {SUB,SUB {N} H,2N +1},n = 0-5,YXYM是满足以下条件的数字:0.2 <= X <= 0.4,0.0 <= M <=4。它是由一种具有相对于铝的摩尔比RAT Ni或Co(二价阳离子)的合成混合物制备的(摩尔比为1:1至10:1的CATION三价阳离子(一价阳离子),0.1:1至1.2:1的阴离子单羧酸铝(CATION三价)和其他可选的阴离子。该方法包括在淤浆中使包含NI(或钴),铝阳离子和阴离子一元羧酸的混合物反应至小于40 CY,pH至少为7 TEMPALTURE。

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