首页> 外国专利> QUANTUM DOTS OF SILVER SULPHIDE RADIATING IN THE NEAR INFRARED SPECTRUM, METHOD FOR PRODUCING THEM AND APPLICATION IN BIOLOGY

QUANTUM DOTS OF SILVER SULPHIDE RADIATING IN THE NEAR INFRARED SPECTRUM, METHOD FOR PRODUCING THEM AND APPLICATION IN BIOLOGY

机译:红外光谱中硫化银辐射的量子点,制备方法及在生物学中的应用

摘要

1. Quantum dots of silver sulfide emitting in the near infrared region of the spectrum, characterized in that the quantum dots of silver sulfide contain hydrophilic groups attached to their surface, and the hydrophilic groups are obtained from a mercapto-containing hydrophilic reagent, and the hydrophilic reagent is selected from mercaptoacetic acid, mercaptopropionic acid , cysteine, cysteamine, thioctic acid and ammonium mercaptoacetate, or any combination thereof. 2. A method for producing silver sulfide quantum dots emitting in the near infrared region of the spectrum, characterized in that it includes the following steps: 1) obtaining hydrophobic silver sulfide quantum dots; and 2) carrying out the reaction of hydrophobic silver sulfide quantum dots from step 1) with a stoichiometric or excess mercapto-containing hydrophilic reagent in a polar organic solvent to ensure the attachment of hydrophilic groups to the surface of the quantum dots to obtain hydrophilic silver sulfide quantum dots emitting in the near infrared region of the spectrum; the hydrophilic reagent is selected from mercaptoacetic acid, mercaptopropionic acid, cysteine, cysteamine, thioctic acid and m ammonium ercaptoacetate or any combination thereof. 3. A method for producing silver diode quantum dots emitting in the near infrared region of claim 2, wherein in step 2) the hydrophobic silver diode quantum dots react with a mercapto-containing hydrophilic reagent in a polar organic solvent at a temperature ranging from 2 ° C to 80 ° C, over�
机译:1.在光谱的近红外区域中发射的硫化银的量子点,其特征在于,所述硫化银的量子点在其表面上含有亲水基团,并且所述亲水基团是从含巯基的亲水剂中获得的,并且亲水试剂选自巯基乙酸,巯基丙酸,半胱氨酸,半胱胺,硫辛酸和巯基乙酸铵,或其任何组合。 2.一种制备在光谱的近红外区域发射的硫化银量子点的方法,其特征在于,包括以下步骤:1)获得疏水的硫化银量子点。 2)在极性有机溶剂中,使步骤1)的疏水性硫化银量子点与化学计量的或过量的含巯基的亲水性试剂反应,以确保亲水性基团附着于量子点的表面,从而获得亲水性银。在光谱的近红外区域发射的硫化物量子点;亲水试剂选自巯基乙酸,巯基丙酸,半胱氨酸,半胱胺,硫辛酸和巯基乙酸铵或它们的任何组合。 3.根据权利要求2所述的制备在近红外区域内发射的银二极管量子点的方法,其中在步骤2)中,所述疏水性银二极管量子点在极性有机溶剂中与含巯基的亲水性试剂在2℃的温度下反应。 °C至80°C以上。

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