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Zn3(BDC)3Cu(SalPycy) and Zn3(CDC)3Cu(SalPycy)—enantiopure mixed metal-organic frameworks for selective separations and enantioselective recognition
Zn3(BDC)3Cu(SalPycy) and Zn3(CDC)3Cu(SalPycy)—enantiopure mixed metal-organic frameworks for selective separations and enantioselective recognition
Disclosed herein are mixed metal-organic frameworks, Zn3(BDC)3[Cu(SalPycy)] and Zn3(CDC)3[Cu(SalPycy)], wherein BDC is 1,4-benzenedicarboxylate, CDC is 1,4-cyclohexanedicarboxylate, and SalPyCy is a ligand of the formula:; These are useful for applications such as selective gas storage, selective molecular separations, and selective detection of molecules, including enantioselective applications thereof.
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