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METHOD FOR DETERMINATION OF ENANTIOMERIC EXCESS OF CHIRAL COMPOUNDS (VERSIONS)

机译:测定手性化合物(版本)对映体过量的方法

摘要

FIELD: chemistry.;SUBSTANCE: one of the methods for determination of enantiomeric excess of chiral compounds involves luminescence spectrum measurement of the tested samples, and luminescence spectrum measurement for samples with known enantiomeric composition, comparison of the obtained results, and plotting of correlations between luminescence intensity and enantiomeric excess. The second method for determination of enantiomeric excess of chiral compounds also involves doping of the tested samples with low concentration luminescent probes, and doping of chiral compounds with known enantiomeric composition with the same luminescent probes of the same concentration.;EFFECT: method for determination of enantiomeric excess of chiral compounds, not requiring secondary asymmetric reagents and polarisation determination.;25 cl, 11 dwg, 7 tbl
机译:物质:手性化合物对映异构体过量的测定方法之一是对被测样品的发光光谱进行测量,对映体组成已知的样品进行发光光谱测量,比较所得结果,并绘制相关图发光强度和对映体过量。测定手性化合物对映异构体过量的第二种方法还包括用低浓度发光探针掺杂被测样品,并用相同浓度的相同发光探针掺杂已知对映体组成的手性化合物。对映体过量的手性化合物,不需要次级不对称试剂和极化测定。; 25 cl,11 dwg,7 tbl

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