首页> 外国专利> METHOD FOR MANUFACTURING ZEOLITE ADSORBENT HAVING EXCELLENT ADSORPTION OF CRESOL AND ZEOLITE ADSORBENT MANUFACTURED THEREBY

METHOD FOR MANUFACTURING ZEOLITE ADSORBENT HAVING EXCELLENT ADSORPTION OF CRESOL AND ZEOLITE ADSORBENT MANUFACTURED THEREBY

机译:具有优异的对树脂的吸附性能的沸石吸附剂及其制备的沸石吸附剂

摘要

The present invention relates to a zeolite adsorbent having excellent adsorption of cresol, and a manufacturing method thereof, and more specifically, to a zeolite adsorbent for separation of cresol, particularly, for industrial production of m-cresol and p-cresol, a manufacturing method thereof, and a method for separating cresol isomers. The manufacturing method of a zeolite adsorbent having excellent adsorption of cresol comprises: a step (a) of mixing distilled water with a barium salt precursor having a barium ion to aluminum rate of 1 to 4, a potassium salt precursor having a potassium ion to aluminum rate of 0.1 to 2, and a zeolite having the aluminum to produce a solution; a step (b) of heating the solution to 25 to 78°C to keep the solution at the same temperature for 30 minutes to 3 hours, thereby performing ion exchange reaction; a step (c) of washing the solution subjected to the ion exchange reaction with distilled water; and a step (d) of filtering the solution washed with distilled water to recover the filtered adsorbent. In addition, provided is a zeolite adsorbent having excellent adsorption of cresol, in which an amount of adsorbed cresol per unit gram of the zeolite adsorbent is 0.12 to 1.5 g.;COPYRIGHT KIPO 2018
机译:本发明涉及对甲酚的吸附性优异的沸石吸附剂及其制造方法,更具体地,涉及一种用于分离甲酚的沸石吸附剂,特别是对间甲酚和对甲酚的工业生产而言,及其分离甲酚异构体的方法。具有良好的对甲酚吸附性的沸石吸附剂的制造方法包括:步骤(a):将蒸馏水与钡离子与铝的比率为1至4的钡盐前体混合,钾离子与铝的钾盐前体混合。比率为0.1至2,以及具有铝以产生溶液的沸石;步骤(b),将溶液加热至25至78℃,使溶液在相同温度下保持30分钟至3小时,从而进行离子交换反应;步骤(c):用蒸馏水洗涤进行了离子交换反应的溶液。步骤(d),将用蒸馏水洗涤后的溶液过滤,回收过滤后的吸附剂。此外,提供了一种具有优异的对甲酚吸附性的沸石吸附剂,其中每克沸石吸附剂吸附的甲酚量为0.12至1.5 g.COPYRIGHT KIPO 2018

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