Preliminary Investigation of Paleochannels and Groundwater Specific Conductance using Direct-Current Resistivity and Surface-Wave Seismic Geophysical Surveys at the Standard Chlorine of Delaware, Inc., Superfund Site, Delaware City, Delaware, 2008

摘要

The U.S. Geological Survey (USGS), in cooperation with Region III of the U.S. Environmental Protection Agency (USEPA) and the State of Delaware, is conducting an ongoing study of the water-quality and hydrogeologic properties of the Columbia and Potomac aquifers and the extent of cross-aquifer contamination with benzene; chlorobenzene; 1,2-dichlorobenzene; 1,4-dichlorobenzene; and hydrogen chloride (hydrochloric acid when dissolved in water) in the vicinity of the Standard Chlorine of Delaware, Inc. (SCD), Superfund Site, Delaware City, Delaware. Surface geophysical surveys and well data were used to identify and correlate low-permeability units (clays) across the site and to search for sand and gravel filled paleochannels that are potential conduits and receptors of contaminated groundwater and (or) Dense Non-Aqueous Phase Liquid (DNAPL) contaminants. The combined surveys and well data were also used to characterize areas of the site that have groundwater with elevated (greater than 1,000 microsiemens per centimeter) specific conductance (SC) as a result of contamination. The most electrically conductive features measured with direct-current (DC) resistivity at the SCD site are relatively impermeable clays and permeable sediment that are associated with elevated SC in groundwater. Many of the resistive features include paleochannel deposits consisting of coarse-grained sediments that are unsaturated, have low (less than 200 microsiemens per centimeter) SC pore water, or are cemented. Groundwater in uncontaminated parts of the Columbia aquifer and of the Potomac aquifer has a low SC. Specific-conductance data from monitoring wells at the site were used to corroborate the DC-resistivity survey results. For comparison with DC-resistivity surveys, multi-channel analysis of surface wave (MASW) surveys were used and were able to penetrate deep enough to measure the Columbia aquifer, which is known to have elevated SC in some places. MASW survey results respond to solid material stiffness; clays and cemented sediments will have a higher velocity than silts, sands, and gravels (in order of increasing hydraulic conductivity).