Effect of monodisperse Cu_2S nanodisks on photovoltaic performance of P3HT/PCBM polymer solar cells

摘要

Hybrid solar cells using monodisperse Cu_2S nanodisks compositing with the mixture of poly (3-hexylthiophene):l-(3-methoxycarbonyl) propyl-1-pheny 6,6 C61 (P3HT:PCeoBM) as the active layer have been fabricated and characterized. The hybrid solar cells exhibit the highest efficiency of 1.35 when the weight ratio of P3HT:PC_(60)BM:Cu_2S is 1:0.8:0.224. The power conversion efficiency (PCE) of nanocomposite device is increased 22.7 comparing with that of the device based on pure P3HT/PC_(60)BM. It is due to that the effect of high-quality Cu_2S nanodisks with good dispersity contributes the increased electronic transportation in the active layer and results in the enhancement in photovoltaic performance. We also investigated the morphology of photoactive layer by microscope; it is found that the dispersity of nanomaterial in active layer is very important for device performance and improvement of carrier mobility.