A Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon

Oliver J. Cooper; Ashley J. Wooles; Jonathan McMaster

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A Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon

机译：一种具有扭曲跨平面四配位碳的单体二硫二烷基二元

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摘要

The proposal of tetrahedral geometry for four-coordinate carbon (I) by van't Hoff in 1874 was a seminal advance in the understanding of the structural properties of molecules, and this theory subsequently became a cornerstone of organic chemistry.

机译：1874 年，范特霍夫提出了四配位碳（I）的四面体几何，这是理解分子结构性质的开创性进展，该理论随后成为有机化学的基石。

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来源
《Angewandte Chemie》 |2010年第32期|5570-5573|共4页
作者
Oliver J. Cooper; Ashley J. Wooles; Jonathan McMaster;
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作者单位

School of Chemistry, University of Nottingham University Park, Nottingham, NG7 2RD (UK);

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原文格式 PDF
正文语种英语
中图分类应用化学;
关键词
lithtuni; methandiide; N; P ligands; planar four-coordinate carbon; structure elucidation;

机译：利斯图尼;甲基二胺;N;P配体;平面四坐标碳;结构解析;

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1. Monomeric three- and four-coordinate magnesium amides [J] . Sebestl JL., Heeg MJ., Winter CH.Nadasdi TT. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第6期

机译：Monomeric three- and four-coordinate magnesium amides
2. MONOMERIC, FOUR-COORDINATE GROUP 4 METAL COMPLEXES WITH CHELATING BIS(TERT-BUTYLAMIDO)CYCLODISILAZANE LIGANDS - SYNTHESES AND MOLECULAR STRUCTURES OF (((MESINBU)-BU-T)(2)((NBU)-BU-T)(2))MCL2 AND (((MESINBU)-BU-T)(2)((NBU)-BU-T)(2))MME2, M=ZR, HF [J] . Grocholl L., Stahl L., Staples RJ.Steinhart P.Johnson A.Huch V. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1997,第20期

机译：MONOMERIC, FOUR-COORDINATE GROUP 4 METAL COMPLEXES WITH CHELATING BIS(TERT-BUTYLAMIDO)CYCLODISILAZANE LIGANDS - SYNTHESES AND MOLECULAR STRUCTURES OF (((MESINBU)-BU-T)(2)((NBU)-BU-T)(2))MCL2 AND (((MESINBU)-BU-T)(2)((NBU)-BU-T)(2))MME2, M=ZR, HF
3. Monomeric magnesium 1-azaallyl and beta;-diketiminato complexes derived from the bis(trimethylsilyl)methyl ligand: The X-ray structure of the four-coordinate planar magnesium complex Mg{N(R)C(But)C(H)R}2 and of Mg({N(R)C(Ph)}2CH)2dagger; [J] . Catherine F. Caro chemical communications . 1997,第15期

机译：Monomeric magnesium 1-azaallyl and beta;-diketiminato complexes derived from the bis(trimethylsilyl)methyl ligand: The X-ray structure of the four-coordinate planar magnesium complex Mg{N(R)C(But)C(H)R}2 and of Mg({N(R)C(Ph)}2CH)2dagger;

A Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon

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