Interface improvement of carbon fiber/methylphenylsilicone resin composites by fiber surface coating of polyhedral oligomeric silsesquioxanes

摘要

To enhance interfacial properties of carbon fibers (CFs)-reinforced methylphenylsilicone resin (MPSR) composites, we introduced an appropriate interface reinforced by trisilanolphenyl-polyhedral oligomeric silsesquioxanes (trisilanolphenyl-POSS) between CFs and MPSR with a liquid phase deposition strategy. Chemical bonds among silanol groups of trisilanolphenyl-POSS, hydroxyl-functionalized CF (CF-OH), and silanol end groups of MPSR in the coating were expected to be formed through condensation reaction during the prepared process. CFs with and without sizing treatment-reinforced MPSR composites were prepared by a compression molding method. X-ray photoelectron spectroscopy revealed that trisilanolphenyl-POSS particles enhanced the contents of fiber surface oxygen-containing groups and silicon-containing functional groups. Scanning electron microscopy and atomic force microscopy images showed that trisilanolphenyl-POSS nanoparticles have been introduced onto the fiber surface obviously and the surface roughness increased sharply. Dynamic contact angle analysis indicated that trisilanolphenyl-POSS-modified sizing agent could improve the fiber wettability and surface energy significantly. Short-beam bending test and impact toughness test results showed that the interlaminar shear strength and impact resistance of the sized CFs composites were enhanced greatly with increasing amplitudes of more than 35 and 27 in comparison with those of untreated CF composites, respectively. Cryo-fractured surface topographies of composites confirmed that interfacial adhesion between CFs and MPSR has been improved after sizing treatment. Meanwhile, the sizing treatment does not decrease single fiber tensile strength.