AbstractWe investigate the effects of convective heat transfer on the thermal history of sediments and petroleum formation within continental rift basins using one‐dimensional mathematical modelling. The transport equations used in this study to describe vertical groundwater flow and conductive/convective heat transfer are solved by the finite element method. Sediment thermal history is quantitatively represented using first‐order rate kinetic expressions for kerogen degradation and an empirical fanning Arrhenius model for apatite fission track annealing. Petroleum generation is also represented in the model by a suite of first‐order rate kinetic expressions. The analysis provides insights into how pore fluid circulation patterns are preserved in the rock record as anomalies in palaeogeothermometric data within continental rifts. Parameters varied in the numerical experiments include the ratio of conductive to convective heat transfer (thermal Peclet number;Pe) and the composition of the disseminated organic matter in the sediment (type II and III kerogen).Quantitative results indicate that vertical groundwater flow rates on the order of a mm/yr cause a change in computed vitrinite reflectance of the rocks and a shift in the depth to oil generation by as much as 3000 m. Differences in thermal gradients between recharge and discharge areas (Pe= 0.6) also change the width of the zone of oil generation by a factor of two. Even more dramatic, however, are the large changes in predicted apatite fission track length distributions and model ages between recharge and discharge areas. For example, a sediment package buried to a depth of 2400 m over 200 Myr within the groundwater recharge column had a fission track length distribution with a computed mean and standard deviation of 12.83 μm and 0.77 μm, respectively. The fission track model age for this sediment package was 209 Ma. The same sediment package in the discharge area has a distribution with a mean track length of 5.68 μm, a standard deviation of 3.37 μm, and a fission track model age of 2.6 Ma.Transient groundwater flow simulations, in which fluid circulation ceases after a period of time within the rift basin, are also presented to illustrate how disturbances in palaeogeothermometric parameters are preserved on geological time‐scales. Vitrinite reflectance profiles require about 10 Myr to return to conductive conditions within groundwater recharge areas while the convective disturbances are preserved indefinitely along the discharge column, as long as further subsidence does not occur. Ancient groundwater flow systems are preserved as anomalies in computed apatite fission track model ages and distributions much longer after groundwater flow stops, relative to organic‐based geothermometers. Significant differences exist in model ages between recharge (145 Ma) and discharge (90 Ma) areas 200 Myr after flow has ceased. However, calculated fission track histogram distributions are virtually identical in recharge and discharge areas after about 50 Myr.Our study suggests that ancient groundwater flow systems can be detected by comparing thermochronometric data between suspected recharge and discharge areas within continental rifts. Vitrinite reflectance profiles, observed offsets in the depth to the onset of petroleum generation, and apatite fission track annealing studies are all well suited for detecting groundwater flow systems which have been relatively long lived (107years). Apatite fission track age data are probably best suited for identifying ancient groundwater flow systems within rifts long (>200 Myr) afte
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