Effect of drawing on creep fracture of polypropylene fibers

摘要

AbstractThe ultimate properties of polypropylene fibers, prepared by drawing the same undrawn fibers to different draw ratios, were determined by the creep fracture method at temperatures from 40 to 120°C. The composite curves of the engineering stress at break, the true stress at break, the ultimate extension ratio were constructed as a function of reduced time to break by assuming time–temperature superposition. The temperature dependence of the shift factoraTused in the superposition could be represented by a single equation of the Williams, Landel, and Ferry form. The composite curves of the true stress at break for the samples with different draw ratios were almost the same independently of draw ratio. The composite curves of the ultimate extension ratio for these samples could be reduced to a single curve by assuming that the ultimate extension ratio evaluated with respect to the unit length of the undrawn fibers were constant independently of draw ratio if the time to break and temperature conditions of the measurement were fixed constant. A possible fracture mechanism is discussed on the basis of the fracture mechanisms proposed by Samuels and Peterl