Abstract Artificial lighting currently consumes approximately one‐fifth of global electricity production. Organic emitters with white persistent RTP have potential for applications in energy‐efficient lighting technologies, due to their ability to harvest both singlet and triplet excitons. Compared to heavy metal phosphorescent materials, they have significant advantages in cost, processability, and reduced toxicity. Phosphorescence efficiency can be improved by introducing heteroatoms, heavy atoms, or by incorporating luminophores within a rigid matrix. White‐light emission can be achieved by tuning the ratio of fluorescence to phosphorescence intensity or by pure phosphorescence with a broad emission spectrum. This review summarizes recent advances in the design of purely organic RTP materials with white‐light emission, describing single‐component and host‐guest systems. White phosphorescent carbon dots and representative applications of white‐light RTP materials are also introduced.
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