Twisted Surfaces in Porous Single Crystals to Deliver Enhanced Catalytic Activity and Stability

摘要

Porous single crystals which combine ordered lattice structures and disordered inter-connected pores would provide an alternative to create twisted surface in porous microstructures. Now, transition-metal nitride Nb(4)N(5)and MoN single crystals are grown on a 2 cm scale to create well-defined active structures at twisted surfaces. High catalytic activity and stability toward non-oxidative dehydrogenation of ethane to ethylene is observed. Unsaturated metal-nitrogen coordination structures including Nb-N-1/5, Nb-N-2/5, Mo-N-1/3, and Mo-N(1/6)at the twisted surface mainly account for the C-H activation with chemisorption of H in molecular ethane at the twisted surface, which not only improves dehydrogenation performance but also avoids the deep cracking of ethane to enhance coking resistance. 11-25 ethane conversion and 98-99 ethylene selectivity is demonstrated without degradation being observed even after the operation of 50 hours.