Dispersion-assisted tunable fluorescence from carbon dots

摘要

In this study, carbon dots (CDs) synthesized by hydrothermal method with amino-rich surface exhibit tunable fluorescence across entire visible range by simply controlling the concentration. A comprehensive comparison has been performed for the first time between concentration-induced aggregation of the single-type CDs and electrostatic-induced agglomeration of opposite-charged CDs in terms of their fluorescence properties. Experimental results show that both the aggregation of CDs and internal absorption filtration are possible causes of the concentration-dependent fluorescence emission. Subsequently, the inter distance of adjacent CDs in their aggregates was enlarged by forming rigid double-stranded DNA (dsDNA) between adjacent CDs through base pairing. It is clear that the contact of CDs induces the changes of fluorescence emission and light absorption. Through a better understanding of the mechanisms behind concentration-induced multicolor emission, this work can provide a novel strategy to develop the advanced applications of CDs.