Realizing Record-High Electroluminescence Efficiency of 31.5 for Red Thermally Activated Delayed Fluorescence Molecules

摘要

Tailor-made red thermally activated delayed fluorescence (TADF) molecules comprised of an electron-withdrawing pyrazino[2,3-f][1,10]phenanthroline-2,3-dicarbonitrile core and various electron-donating triarylamines are developed. They can form intramolecular hydrogen-bonding, which is conducive to improving emission efficiency and promoting horizontal orientation and show near infrared (NIR) emissions (692-710 nm) in neat films and red delayed fluorescence (606-630 nm) with high photoluminescence quantum yields (73-90%) in doped films. They prefer horizontal orientation with large horizontal dipole ratios in films, rendering high optical out-coupling factors (0.39-0.41). Their non-doped OLEDs exhibit NIR lights (716-748 nm) with maximum external quantum efficiencies (eta(ext,max)) of 1.0-1.9%. And their doped OLEDs radiate red lights (606-648 nm) and achieve record-beating eta(ext,max) of up to 31.5%. These new red TADF materials should have great potentials in display and lighting devices.