Synthesis of cetyl trimethyl ammonium bromide (CTAB) capped copper oxide nanocubes for the remediation of organic pollutants using photocatalysis and catalysis

摘要

The aim of this report is to synthesize copper oxide nanocubes (CuO NCs) at room temperature, using sodium borohydride as a reducing agent, and Cetyl Trimethyl Ammonium Bromide (CTAB) as a stabilizing agent. The crystallinity and morphology of the synthesized CuO NCs are investigated via X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscope (TEM). The optical properties were analyzed by means of UV-visible absorbance and Raman spectroscopy. The existence of specific functional groups and structural stability were established via FTIR spectroscopy and thermogravimetric analysis (TGA). Furthermore, the catalytic efficiency of the as-prepared CuO NCs was tested using catalytic and photocatalytic studies of para-nitrophenol (p-NP) reduction and methylene blue (MB) degradation, respectively. The catalytic results demonstrated the nanocubes' excellent catalytic and photocatalytic responses with respect to the abatement of p-NP and MB within 50 s and 240 min, with kinetic rate constants of 3.9 x 10(-2) s(-1) and 6.47 x 10(-3) min(-1), respectively.