Stereolithography (SLA) 3D printing of carbon fiber-graphene oxide (CF-GO) reinforced polymer lattices

摘要

Insufficient mechanical properties of stereolithography (SLA)-printed architected polymer metamaterial limits its wide applications such as in the areas of biomedicine and aerospace. One effective solution is to reinforce the structures with micro- or nano- fibers/particles, but their interfaces are critical for the reinforcement. In this work, a carbon fiber-graphene oxide (CF-GO) polymer composite resin and a mild annealing postprocess have been rationally designed and applied into the manufacturing of oct-truss (OCT) lattices. In situ carbon fiber pulling-out experiment was conducted to exhibit the improve effect of GO on the crosslink of the CF and the polymer matrix interface. We found that the maximum reinforcement was realized when the CF-GO (CF: GO is about 3: 1) content is about 0.8 wt%, followed with annealing. Compared with pure polymer lattices, the compression strength of the CF-GO polymer OCT lattices has been significantly increased from similar to 0.22 to similar to 2.4 MPa, almost 10 times enhancement. Importantly, the compression strength of the CF-GO polymer OCT lattice (3.08 MPa) further increased by similar to 30% after optimized annealing. This work suggests an efficient reinforce strategy for SLA-printed metamaterials, and thus can be valuable for advancing various practical applications of mechanical metamaterials.