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>Detection o micro-toxic elements in commercial coffee brands using optimized dual-pulsed laser-induced spectral analysis spectrometry
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Detection o micro-toxic elements in commercial coffee brands using optimized dual-pulsed laser-induced spectral analysis spectrometry
A fast detection system based on dual-pulsed laser-induced breakdown spectroscopy (DP-LIBS) was successfully developed and optimized for the estimation of micro-toxic element contents in commercial coffee brands to monitor pollution and ensure food safety. A series of 13 various coffee brands were quantitatively analyzed in this study utilizing DP-LIBS and a standard analytical technique like inductively coupled plasma/optical emission spectrometry (ICP-OFS). The micro-toxic elements, such as aluminum (Al), lead (Pb), zinc (Zn), and chromium (Cr), that exist in the coffee brands were exactly identified. We prepared standard matrices in a known concentration in the coffee sample to draw the standard calibration curves for each element, as well as by utilizing a tactic based on the intense line emission of the element of interest as a quantitative analysis. The analytical routines were approved under the expectations that the plasma created by the dual-pulsed lasers was in local thermodynamic equilibrium (LTE) and was optically thin. We investigated the influence of different parametric dependence studies to enhance our DP-LIBS detection sensitivity. Furthermore, the precision of our DP-LIBS data for determining the concentration of micro-toxic elements present in coffee samples was validated via the ICP-OES technique. The results achieved by the DP-LIBS technique were in full agreement with the ICP-OES results. In addition, the estimated limit of detection of our DP-LIB spectrometer for Al, Pb, Zn, and Cr were 105.13 +/- 07, 90.17 +/- 12, 83.58 +/- 15, and 68.78 +/- 09 mu g L-1, respectively. The suggested protocols demonstrated the excellent benefits of the DP-LIBS for the detection of micro-toxic elements existing in coffee and for checking the purity and quality of food products. (C) 2018 Optical Society of America
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机译:成功开发了一种基于双脉冲激光诱导的击穿光谱(DP-LIBS)的快速检测系统,并优化了商业咖啡品牌中的微毒性元素内容,以监测污染并确保食品安全。在本研究中,利用DP-LIB和耦合等离子体/光发射光谱(ICP)的标准分析技术定量分析了一系列各种咖啡品牌。咖啡品牌中存在的微毒性元素如铝(Al),铅(Pb),锌(Zn)和铬(Cr)。我们在咖啡样品中以已知的浓度制备标准矩阵,以绘制每个元件的标准校准曲线,以及利用基于感兴趣元素的强烈排放作为定量分析的策略。在预期的期望下批准了分析程序,即双脉冲激光器产生的等离子体是在局部热力学平衡(LTE)中并且光学薄。我们调查了不同参数依赖性研究的影响,提高了DP-LIBS检测灵敏度。此外,通过ICP-OES技术验证了用于确定咖啡样品中存在的微毒性元素浓度的DP-LIBS数据的精度。 DP-LIBS技术实现的结果与ICP-OES结果完全一致。此外,对于Al,Pb,Zn和Cr的DP-Lib光谱仪检测估计的检测限为105.13 +/- 07,90.17 +/- 12,83.58 +/- 15和68.78 +/- 09 mu g L-1分别。建议的协议证明了DP-LIB的优异益处,用于检测咖啡中存在的微毒性元素和检查食品的纯度和质量。 (c)2018年光学学会
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