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Numerical study on the scattering property of porous polymer structures via supercritical CO2 microcellular foaming

机译:超临界CO2微孔发泡多孔聚合物结构散射性能的数值研究

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摘要

Disordered porous polymer structures have gained tremendous attention due to their wide applications in various fields. As a simple yet versatile technique, supercritical CO2 microcellular foaming has been proposed to fabricate highly scattering porous polymer films, which have been used to enhance the efficiency of quantum dots (QDs) films. In the foaming process, numerous enclosed pores are generated, which induce significant scattering, underpinning the efficiency enhancement in optoelectronic devices. However, the scattering property of foamed porous structures has still not been well investigated, and effective guidelines for engineering the porous structures are still not available. In this work, we use Mie scattering theory and ray-tracing simulation to analyze the optical property of a single pore, pore assembly, and porous film. Furthermore, it is demonstrated that the scattering scheme in the porous QD films leads to a large enhancement of excitation light absorption and QD emission extraction. It is envisioned that our work will contribute to the engineering guidelines of porous structures and boost the application of porous structures in similar fields. (C) 2020 Optical Society of America
机译:由于它们在各种领域的广泛应用,无序的多孔聚合物结构具有巨大的关注。作为一种简单而多功能的技术,已经提出了超临界CO2微孔发泡以制造高度散射的多孔聚合物膜,这些聚合物膜已经用于增强量子点(QDS)膜的效率。在发泡过程中,产生许多封闭的孔,诱导显着的散射,支撑光电器件中的效率增强。然而,泡沫多孔结构的散射性仍未得到很好的研究,并且仍然不可用的工程工程准则。在这项工作中,我们使用MIE散射理论和射线跟踪模拟来分析单孔,孔组件和多孔膜的光学性质。此外,证明多孔QD膜中的散射方案导致激发光吸收和QD发射提取的大大提高。设想我们的工作将有助于多孔结构的工程指导,并提高多孔结构在类似领域的应用。 (c)2020美国光学学会

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    《Applied optics》 |2020年第14期|共9页
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