Synthesis and Characterization of Stable Ruthenabenzenes

摘要

Transition-metal-containing metallabenzenes are an interesting class of compounds because they exhibit chemical properties of both organometallic compounds and aromatic organic compounds.The first stable transition-metal-con-taining metallabenzenes were reported in 1982 by Roper et al.Since then a number of stable metallabenzenes have been successfully isolated and characterized.Most of the well-characterized stable metallabenzenes are those with a transition metal atom from the third transition series,especially osmium,indium,and platinum.