Choices of Iron and Copper: Cooperative Selection during Self-Assembly

摘要

The technique of subcomponent self-assembly is emerging at the intersection of dynamic covalent and metallo-supra-molecular chemistry.In subcomponent self-assembly two hierarchical self-assembly reactions occur as parts of the same overall process: Intraligand (generally C=N) bonds form at the same time as metal-ligand bonds,thus bringing molecular and supramolecular structures into being at the same time.