Hydroamination/Hydrosilylation Sequence Catalyzed by Titanium Complexes

摘要

Over the past few years, strategies for the one-pot synthesis of interesting target molecules that require more than one chemical transformation have gained increasing attention. In this context, the use of a single catalyst for a combination of different catalytic reactions (multifunctional catalysis) is one of the most promising approaches.[1] One way to realize a corresponding strategy is the combination of different transitions-metal-catalyzed reactions into a sequence. In this case, a single catalyst that mediates several consecutive reactions is used for the one-pot process. Each individual reaction is initiated by a change of the reaction conditions or the addition of a new reagent.[2]