Water‐Mediated Synthesis of a Superionic Halide Solid Electrolyte

摘要

Abstract > To promote the development of solid‐state batteries, polymer‐, oxide‐, and sulfide‐based solid‐state electrolytes (SSEs) have been extensively investigated. However, the disadvantages of these SSEs, such as high‐temperature sintering of oxides, air instability of sulfides, and narrow electrochemical windows of polymers electrolytes, significantly hinder their practical application. Therefore, developing SSEs that have a high ionic conductivity (10 ?3 ?S?cm ?1 ), good air stability, wide electrochemical window, excellent electrode interface stability, low‐cost mass production is required. Herein we report a halide Li + superionic conductor, Li <sub>3</sub> InCl <sub>6</sub> , that can be synthesized in water. Most importantly, the as‐synthesized Li <sub>3</sub> InCl <sub>6</sub> shows a high ionic conductivity of 2.04×10 ?3 ?S?cm ?1 at 25?°C. Furthermore, the ionic conductivity can be recovered after dissolution in water. Combined with a LiNi <sub>0.8</sub> Co <sub>0.1</sub> Mn <sub>0.1</sub> O <sub>2</sub> cathode, the solid‐state Li battery shows good cycling stability. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 为了促进固态电池的开发，已经广泛研究了聚合物，氧化物和硫化物的固态电解质（SSES）。然而，这些SSE的缺点，例如高温烧结氧化物，硫化物的空气不稳定，以及聚合物电解质的窄电化学窗口，显着阻碍了它们的实际应用。因此，显影具有高离子电导率的SSE（＆ 10 ？3 </ sup> ？s？cm ？1 </ sup> ），良好的空气稳定性，宽电化学窗口，优异的电极接口稳定性，需要低成本的批量生产。在此，我们报告卤化物李 + </ sup> 超前导体，李 <sub> 3 </ sub> 含 <sub> 6 </ sub> ，可以在水中合成。最重要的是，AS合成的李 <sub> 3 </ sub> 含 <sub> 6 </ sub> 显示高离子电导率为2.04×10 ？3 </ sup> ？s？cm ？1 </ sup> 在25°C时。此外，可以在水中溶解后回收离子电导率。结合亚麻 <sub> 0.8 </ sub> CO. <sub> 0.1 </ sub> MN. <sub> 0.1 </ sub> O. <sub> 2 </ sub> 阴极，固态Li电池显示出良好的循环稳定性。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2019年第46期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=all-solid-state battery&option=203" rel="nofollow">all-solid-state battery;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=aqueous synthesis&option=203" rel="nofollow">aqueous synthesis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=halide solid electrolyte&option=203" rel="nofollow">halide solid electrolyte;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ionic conductivity&option=203" rel="nofollow">ionic conductivity;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium&option=203" rel="nofollow">lithium;</a> </p> <div class="translation"> 机译：全固态电池;水性合成;卤化物固体电解质;离子电导率;锂; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028164674.html">Back Cover: Water‐Mediated Synthesis of a Superionic Halide Solid Electrolyte (Angew. 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<a href="/journal-cn-7872/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 石化技术 </a> </span> <span> . 2017</span><span>,第010期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_china-medical-device-information_thesis/020127203561.html">医用聚氨酯导管表面亲水涂层的合成研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王小妹&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王小妹</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=伍雪芬&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,伍雪芬</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周宇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,周宇</a> <span> <a href="/journal-cn-5366/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国医疗器械信息 </a> </span> <span> . 2016</span><span>,第010期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-chemical-engineering-english_thesis/0201292507007.html">陶瓷膜表面Ca-Mg-Al水滑石的原位合成与表征及其在生物柴油制备中的应用（英文）</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐威&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 徐威</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=高李璟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,高李璟</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=姜枫&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,姜枫</a> <span> <a href="/journal-cn-52877/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化学工程学报：英文版 </a> </span> <span> . 2015</span><span>,第6期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_materials-science-technology_thesis/0201211557308.html">表面活性剂辅助水热合成异形薄水铝石</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=蔡卫权&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 蔡卫权</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李会泉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李会泉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张懿&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张懿</a> <span> <a href="/journal-cn-7650/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 材料科学与工艺 </a> </span> <span> . 2008</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chemical-research-application_thesis/0201235580887.html">新型表面活性剂聚乙二醇醚基双苯磺酸钠的合成及在催化水相三组分一锅法Mannich反应中的应用</a> <b>[J]</b> <span> <a 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