A Sustainable Solid Electrolyte Interphase for High‐Energy‐Density Lithium Metal Batteries Under Practical Conditions

Zhang Xue‐Qiang; Li Tao; Li Bo‐Quan; Zhang Rui; Shi Peng; Yan Chong; Huang Jia‐Qi; Zhang Qiang

摘要

Abstract > High‐energy‐density Li metal batteries suffer from a short lifespan under practical conditions, such as limited lithium, high loading cathode, and lean electrolytes, owing to the absence of appropriate solid electrolyte interphase (SEI). Herein, a sustainable SEI was designed rationally by combining fluorinated co‐solvents with sustained‐release additives for practical challenges. The intrinsic uniformity of SEI and the constant supplements of building blocks of SEI jointly afford to sustainable SEI. Specific spatial distributions and abundant heterogeneous grain boundaries of LiF, LiN <sub> x </sub> O <sub> y </sub> , and Li <sub>2</sub> O effectively regulate uniformity of Li deposition. In a Li metal battery with an ultrathin Li anode (33?μm), a high‐loading LiNi <sub>0.5</sub> Co <sub>0.2</sub> Mn <sub>0.3</sub> O <sub>2</sub> cathode (4.4?mAh?cm ?2 ), and lean electrolytes (6.1?g?Ah ?1 ), 83?% of initial capacity retains after 150 cycles. A pouch cell (3.5?Ah) demonstrated a specific energy of 340?Wh?kg ?1 for 60 cycles with lean electrolytes (2.3?g?Ah ?1 ). </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 由于不存在适当的固体电解质相互作用（SEI），高能密度Li金属电池在实际条件下患有短寿命，例如有限的锂，高负载阴极和瘦电解质。在此，通过将氟化的共溶剂与持续释放的添加剂组合以进行实际挑战，合理地设计了可持续的SEI。 SEI的内在均匀性和SEI建筑块的恒定补充，共同提供可持续的SEI。 LiL，LIN的特定空间分布和丰富的异构晶界 <sub> x </ i> </ sub> O. <sub> Y </ I> </ sub> 和李 <sub> 2 </ sub> o有效地调节LI沉积的均匀性。在带有超薄锂阳极（33Ωμm）的Li金属电池中，高负荷的LINI <sub> 0.5 </ sub> CO. <sub> 0.2 </ sub> MN. <sub> 0.3 </ sub> O. <sub> 2 </ sub> 阴极（4.4？mah？cm ？2 </ sup> ）和瘦电解质（6.1？g？啊？1 </ sup> ），83？％的初始容量在150次循环后保持。小袋细胞（3.5？ah）显示了340的特定能量？wh？kg ？1 </ sup> 60个循环，瘦电解质（2.3？G？啊？1 </ sup> ）。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第8期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Xue‐Qiang&option=202" target="_blank" rel="nofollow">Zhang Xue‐Qiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Tao&option=202" target="_blank" rel="nofollow">Li Tao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Bo‐Quan&option=202" target="_blank" rel="nofollow">Li Bo‐Quan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Rui&option=202" target="_blank" rel="nofollow">Zhang Rui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shi Peng&option=202" target="_blank" rel="nofollow">Shi Peng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yan Chong&option=202" target="_blank" rel="nofollow">Yan Chong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Huang Jia‐Qi&option=202" target="_blank" rel="nofollow">Huang Jia‐Qi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Qiang&option=202" target="_blank" rel="nofollow">Zhang Qiang;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Beijing Key Laboratory of Green Chemical Reaction Engineering and TechnologyTsinghua UniversityBeijing 100084 P. R. China;</p> <p>Beijing Key Laboratory of Green Chemical Reaction Engineering and TechnologyTsinghua UniversityBeijing 100084 P. R. China;</p> <p>Beijing Key Laboratory of Green Chemical Reaction Engineering and TechnologyTsinghua UniversityBeijing 100084 P. R. China;</p> <p>Beijing Key Laboratory of Green Chemical Reaction Engineering and TechnologyTsinghua UniversityBeijing 100084 P. R. China;</p> <p>Beijing Key Laboratory of Green Chemical Reaction Engineering and TechnologyTsinghua UniversityBeijing 100084 P. R. China;</p> <p>Advanced Research Institute of Multidisciplinary ScienceBeijing Institute of TechnologyBeijing 100081 P. R. China;</p> <p>Advanced Research Institute of Multidisciplinary ScienceBeijing Institute of TechnologyBeijing 100081 P. R. China;</p> <p>Beijing Key Laboratory of Green Chemical Reaction Engineering and TechnologyTsinghua UniversityBeijing 100084 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrolytes&option=203" rel="nofollow">electrolytes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium batteries&option=203" rel="nofollow">lithium batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=pouch cells&option=203" rel="nofollow">pouch cells;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=solid electrolyte interphases&option=203" rel="nofollow">solid electrolyte interphases;</a> </p> <div class="translation"> 机译：电解质;锂电池;袋细胞;固体电解质互相; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028160738.html">Inside Back Cover: A Sustainable Solid Electrolyte Interphase for High‐Energy‐Density Lithium Metal Batteries Under Practical Conditions (Angew. 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Ko&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jesse S. 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Energy Mater. 26/2018)</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sean M. Wood&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sean M. Wood,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chengcheng Fang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chengcheng Fang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Eric J. Dufek&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Eric J. Dufek,</a> <span>2018</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：电池：预测锂金属二次电池中的日历老化：固体电解质相互作用和稳定性的影响（ADV。能源母体。26/2018）</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_yunnan-electric-power_thesis/0201293724969.html">能量密度高达500 Wh/kg液体锂硫和锂硒电池采用固体电解质</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . </a> <span> <a href="/journal-cn-15890/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 云南电力技术 </a> </span> <span> . 2019</span><span>,第S01期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-power-sources_thesis/0201275597621.html">无机固体电解质用于锂及锂离子蓄电池的研究进展Ⅱ玻璃态锂无机固体电解质</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑洪河&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 郑洪河</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=曲群婷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,曲群婷</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=石静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,石静</a> <span> <a href="/journal-cn-8483/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 电源技术 </a> </span> <span> . 2007</span><span>,第012期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201294725445.html">固态锂电池中金属锂负极与固体电解质界面的关键挑战</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=胡晨晨&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 胡晨晨</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=罗巍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,罗巍</a> <span> <a href="/journal-cn-57080/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 分析科学学报 </a> </span> <span> . 2019</span><span>,第6期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_telecom-power-technology_thesis/0201236904325.html">高能量密度锂离子电池正极材料镍钴铝酸锂技术发展</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邹连荣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 邹连荣</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=田娟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,田娟</a> <span> <a href="/journal-cn-8775/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 通信电源技术 </a> </span> <span> . 2016</span><span>,第006期</span> </span> </div> </li> <li> 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<span>机译：释放结合在电池单元模块的可再充电的电化学储能电池的固体电解质相间或固体电解质相间类层中的金属离子的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130424020440.html">LITHIUM METAL SOLID BODY, LITHIUM METAL FILM MADE OF THE SAME, SOLID ELECTROLYTE MEMBRANE-LITHIUM ELECTRODE ASSEMBLY INCLUDING THE METAL FILM, LITHIUM AIR BATTERY PROVIDED WITH THE SOLID ELECTROLYTE MEMBRANE-LITHIUM ELECTRODE ASSEMBLY, AND METHOD FOR MANUFACTURING THE SOLID ELECTROLYTE MEMBRANE-LITHIUM ELECTRODE ASSEMBLY</a> <b>[P]</b> . <span> 外国专利：  JP2012150909A </span> <span> . 2012-08-09</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：锂金属固体，由相同金属制成的锂膜，包括金属膜的固体电解质膜-锂电极组件，由固体电解质膜电解质膜-电解质膜制成的锂空气电池和方法部件 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130404527151.html">ARTIFICIAL SOLID ELECTROLYTE INTERPHASE OF METALLIC ANODE FOR SECONDARY BATTERY 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