Single‐Atom Iron Catalysts on Overhang‐Eave Carbon Cages for High‐Performance Oxygen Reduction Reaction

Hou Chun‐Chao; Zou Lianli; Sun Liming; Zhang Kexin; Liu Zheng; Li Yinwei; Li Caixia; Zou Ruqiang; Yu Jihong; Xu Qiang

摘要

Abstract >Single‐atom catalysts have drawn great attention, especially in electrocatalysis. However, most of previous works focus on the enhanced catalytic properties via improving metal loading. Engineering morphologies of catalysts to facilitate mass transport through catalyst layers, thus increasing the utilization of each active site, is regarded as an appealing way for enhanced performance. Herein, we design an overhang‐eave structure decorated with isolated single‐atom iron sites via a silica‐mediated MOF‐templated approach for oxygen reduction reaction (ORR) catalysis. This catalyst demonstrates superior ORR performance in both alkaline and acidic electrolytes, comparable to the state‐of‐the‐art Pt/C catalyst and superior to most precious‐metal‐free catalysts reported to date. This activity originates from its edge‐rich structure, having more three‐phase boundaries with enhanced mass transport of reactants to accessible single‐atom iron sites (increasing the utilization of active sites), which verifies the practicability of such a synthetic approach. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >单原子催化剂具有极大的关注，特别是在电殖分析中。然而，以前的大多数作品通过改善金属荷载，重点是增强的催化性能。催化剂的工程形态，以促进通过催化剂层的质量输送，从而增加每个活性位点的利用，被认为是增强性能的吸引力。在此，我们设计了通过二氧化硅介导的MOF模型方法用分离的单原子熨斗部位装饰的悬垂结构，用于氧还原反应（ORR）催化。该催化剂在碱性和酸性电解质中表现出优异的ORR性能，与最新的Pt / C催化剂相当，并且优于迄今为止报道的最珍贵的无金属催化剂。该活动源自其边缘结构，具有更多的三相边界，具有增强的反应物的质量转运，可访问的单原子熨斗部位（增加有源部位的利用），这验证了这种合成方法的实用性。</ P> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第19期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hou Chun‐Chao&option=202" target="_blank" rel="nofollow">Hou Chun‐Chao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zou Lianli&option=202" target="_blank" rel="nofollow">Zou Lianli;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sun Liming&option=202" target="_blank" rel="nofollow">Sun Liming;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Kexin&option=202" target="_blank" rel="nofollow">Zhang Kexin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Zheng&option=202" target="_blank" rel="nofollow">Liu Zheng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Yinwei&option=202" target="_blank" rel="nofollow">Li Yinwei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Caixia&option=202" target="_blank" rel="nofollow">Li Caixia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zou Ruqiang&option=202" target="_blank" rel="nofollow">Zou Ruqiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yu Jihong&option=202" target="_blank" rel="nofollow">Yu Jihong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xu Qiang&option=202" target="_blank" rel="nofollow">Xu Qiang;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL)National Institute of Advanced Industrial Science and Technology (AIST)Sakyo-ku Kyoto 606-8501 Japan;</p> <p>AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL)National Institute of Advanced Industrial Science and Technology (AIST)Sakyo-ku Kyoto 606-8501 Japan;</p> <p>AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL)National Institute of Advanced Industrial Science and Technology (AIST)Sakyo-ku Kyoto 606-8501 Japan;</p> <p>Beijing Key laboratory for Theory and Technology of Advanced Battery MaterialsPeking UniversityBeijing 100871 P. R. China;</p> <p>Inorganic Functional Materials Research InstituteNational Institute of Advanced Industrial Science and Technology (AIST)2266-98 Anagahora Shimoshidami Moriyamaku Nagoya Aichi 463-8560 Japan;</p> <p>Laboratory of Quantum Materials Design and ApplicationJiangsu Normal UniversityXuzhou 221116 P. R. China;</p> <p>AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL)National Institute of Advanced Industrial Science and Technology (AIST)Sakyo-ku Kyoto 606-8501 Japan;</p> <p>Beijing Key laboratory for Theory and Technology of Advanced Battery MaterialsPeking UniversityBeijing 100871 P. R. China;</p> <p>State Key Laboratory of Inorganic Synthesis and Preparative ChemistryJilin UniversityChangchun 130012 P. R. China;</p> <p>AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL)National Institute of Advanced Industrial Science and Technology (AIST)Sakyo-ku Kyoto 606-8501 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemistry&option=203" rel="nofollow">electrochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal–organic frameworks&option=203" rel="nofollow">metal–organic frameworks;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxygen reduction reaction&option=203" rel="nofollow">oxygen reduction reaction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=single-atom catalysis&option=203" rel="nofollow">single-atom catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=transition metals&option=203" rel="nofollow">transition metals;</a> </p> <div class="translation"> 机译：电化学;金属 - 有机框架;氧还原反应;单原子催化;过渡金属; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162085.html">Cover Picture: Single‐Atom Iron Catalysts on Overhang‐Eave Carbon Cages for High‐Performance Oxygen Reduction Reaction (Angew. 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Chen Sheng</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈盛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈盛</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bi Jiyu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Bi Jiyu</a> <span> <a href="/conference-cn-6815/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十届全国博士生学术年会 </a> <span> <span> . 2012</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315995443.html">激光合成高性能钯纳米颗粒催化剂应用于氧还原反应</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=林靖洋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 林靖洋</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120113005246.html">一种氧还原铁–氮化四铁@单原子铁和氮共掺杂无定形碳-炭黑复合催化剂及其制备和应用</a> <b>[P]</b> . <span> 中国专利： CN113054210A </span> <span> . 2021-06-29</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120113535304.html">氮碳材料锚定的铁单原子催化剂在催化醇的氨氧化制腈反应中的应用</a> <b>[P]</b> . <span> 中国专利： CN113559904A </span> <span> . 2021-10-29</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130500457050.html">A catalyst for a carbon dioxide electrolytic reduction reaction or a nitrogen electrolytic reduction reaction, a method for producing a catalyst for a carbon dioxide electrolytic reduction reaction or a nitrogen electrolytic reduction reaction, and an electrode for a carbon dioxide electrolytic reduction reaction or a nitrogen electrolytic reduction reaction.</a> <b>[P]</b> . <span> 外国专利：  JP2021115501A </span> <span> . 2021-08-10</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：二氧化碳电解还原反应的催化剂或氮电解还原反应，其制备用于二氧化碳电解还原反应的催化剂或氮电解还原反应，以及用于二氧化碳电解还原反应的电极或氮电解还原反应。 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130414120497.html">Manufacturing method of oxygen reduction reaction catalysts and catalysts thereof, Cathode using oxygen reduction reaction catalysts</a> <b>[P]</b> . <span> 外国专利：  KR101505285B1 </span> <span> . 2015-03-24</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：氧还原反应催化剂的制造方法及其催化剂，使用氧还原反应催化剂的阴极 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130418004211.html">MANUFACTURING METHOD OF OXYGEN REDUCTION REACTION CATALYSTS AND CATALYSTS THEREOF, CATHODE USING OXYGEN REDUCTION REACTION CATALYSTS</a> <b>[P]</b> . <span> 外国专利：  US2013323610A1 </span> <span> . 2013-12-05</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：氧还原反应催化剂的制造方法及其催化剂，使用氧还原反应催化剂的阴极 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028161334','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" 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