We report the correction of the shrinkage observed during UV postrecording curing in a holographic solgel material that was recently achieved by the use of various chemical formulations for the composition of the hybrid supporting matrix. We found that a chemical modification of the matrix noticeably attenuates the shrinkage (from 1.3% to 0.4% of the material's initial thickness with the inclusion of just 20% tetramethylorthosilicate), providing a material with improved stability for permanent data storage applications. The holographic properties of samples with different binders are also reported. In addition, a theoretical study has revealed the way by which to compensate for angular deviation in the Bragg condition during UV postrecording by tailoring the binder shrinkage (s), the maximum refractiveindex modulation capability of the photosensitive mixture (Δn), or both.
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