Catalytic Asymmetric Reductive Condensation of N-H Imines: Synthesis of C-2-Symmetric Secondary Amines

Wakchaure Vijay N.; List Benjamin

首页> 外文期刊>Angewandte Chemie >Catalytic Asymmetric Reductive Condensation of N-H Imines: Synthesis of C-2-Symmetric Secondary Amines

【24h】

Catalytic Asymmetric Reductive Condensation of N-H Imines: Synthesis of C-2-Symmetric Secondary Amines

机译：N-H亚胺的催化不对称还原缩合：C-2-对称仲胺的合成

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A highly diastereoselective and enantioselective BrOnsted acid catalyzed reductive condensation of N-H imines was developed. This reaction is catalyzed by a chiral disulfonimide (DSI), uses Hantzsch esters as a hydrogen source, and delivers useful C-2-symmetric secondary amines.

机译：开发了高度非对映选择性和对映选择性的布朗斯台德酸催化的N-H亚胺的还原缩合反应。该反应由手性二磺酰亚胺（DSI）催化，使用汉茨酯作为氢源，并提供有用的C-2-对称仲胺。

著录项

来源
《Angewandte Chemie》 |2016年第51期|共4页
作者
Wakchaure Vijay N.; List Benjamin;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
BrOnsted acids; C-2-symmetric secondary amines; disulfonimide; organocatalysis; reduction;

机译：布朗斯台德酸;C-2-对称仲胺;二磺酰亚胺;有机催化;还原;

相似文献

外文文献
中文文献
专利

1. Catalytic Asymmetric Reductive Condensation of N-H Imines: Synthesis of C-2-Symmetric Secondary Amines [J] . Wakchaure Vijay N., List Benjamin Angewandte Chemie . 2016,第51期

机译：N-H亚胺的催化不对称还原缩合：C-2-对称仲胺的合成
2. Unprecedented catalytic asymmetric reduction of N-H imines [J] . Gosselin F, OShea PD, Roy S, Organic letters . 2005,第2期

机译：空前的N-H亚胺催化不对称还原
3. CATALYTIC OXIDATION OF BENZYLIC AMINES TO IMINES BY M(TPP)CL (M = FE, MN) FOLLOWED BY REDUCTION TO SECONDARY AMINES [J] . Tollari S., Porta F., Fumagalli A. Inorganica Chimica Acta . 1997,第1期

机译：M（TPP）CL（M = FE，MN）催化的苯胺催化氧化成二级胺
4. Catalytic Addition of Alkyne C-H,Amine N-H,and Phosphine P-H Bonds to Carbodiimides:An Efficient Route to Propiolamidines, Guanidines, and Phosphaguanidines [C] . International symposium on fine chemistry and functional polymers . 2008

机译：催化加入炔烃C-H，胺N-H和磷酸p-H键与碳二酰亚胺：高效途径到丙醇脒，胍和磷酰胺
5. Part I. Diastereoselective reductions of cyclic N-diphenylphosphinyl imines to N-diphenylphosphinyl amines using amine boranes. Part II. Studies directed towards the synthesis and reaction of phosphinyl enamides. [D] . Rutkowsky, Susan A. 2000

机译：第一部分：使用胺硼烷将环状N-二苯基膦基亚胺非对映选择性还原为N-二苯基膦基胺。第二部分研究针对次膦酰基烯酰胺的合成和反应。
6. Asymmetric Synthesis of Trifluoromethylated Amines via Catalytic Enantioselective Isomerization of Imines [O] . Yongwei Wu, Li Deng -1

机译：通过亚胺的不对称催化异构化三氟甲基化的胺的不对称合成
7. Unprecedented Catalytic Asymmetric Reduction of N-H Imines [O] . -1

机译：前所未有的催化不对称降低N-H亚胺

Catalytic Asymmetric Reductive Condensation of N-H Imines: Synthesis of C-2-Symmetric Secondary Amines

摘要

著录项

相似文献

相关主题

期刊订阅