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首页> 外文期刊>Angewandte Chemie >CrystallograpMc Snapshots of the Bond-Breaking Isomerization Reactions Involving Nickel(II) Complexes with Hemilablle Ligands
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CrystallograpMc Snapshots of the Bond-Breaking Isomerization Reactions Involving Nickel(II) Complexes with Hemilablle Ligands

机译:涉及镍(II)配合物与半球形配体的断裂键异构化反应的CrystallograpMc快照

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摘要

Hemilabile ligands have been used to prepare a wide variety of complexes, which are important in many fields ranging from catalysis to biomimetic chemistry. These ligands allow coordination complexes to be prepared where one end of the hemilabile ligand is anchored to a metal center, while the other often is involved in fluxional processes.
机译:半不稳定的配体已用于制备多种络合物,这在从催化到仿生化学的许多领域中都很重要。这些配体允许制备配位配合物,其中半不稳定配体的一端固定在金属中心,而另一端经常参与助熔过程。

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