Well-Defined Soluble P~(3-)-Containing Rare-Earth-Metal Compounds

摘要

Transition-metal-phosphorus coordination compounds have attracted intense attention and been extensively studied in the past half century. Such coordination compounds not only have a fundamental bearing on the theory of coordination chemistry, but also are known to have important applications, especially in the area of synthetic chemistry. A great number of transition-metal-phosphorus coordination compounds, including PR_nH_(3-n) (n = 1-3), [PR_nH_(2-n)]~- (n = 1-2), [PR]~(2-), and P~(3-) containing species, have been synthesized.