Assembly of an M3N_5~(2-)Chain by Cycloaddition of a Hydrazinediide and an Azide at Zirconium and its Thermal Fragmentation

摘要

The assembly and fragmentation of nitrogen chains in ionic species and organic compounds,as well as those coordinated to metal centers,have been investigated in the context of new high-energy molecular compounds.As potentially reactive fragments,they have been stabilized by coordination to transition metals.A variety of singly and multiply bonded nitrogen-based molecular fragments have thus acted as ligands in transition-metal compounds.