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Iridium Complexes in Organic Synthesis

机译:有机合成中的铱配合物

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摘要

Catalysis of organic reactions by the platinum group metals is a cornerstone of modern chemistry, in terms of both fundamental research and industrial applications. Of these transition metals, those from the 4d series (Ru, Rh, Pd) are generally perceived to be the more active catalysts for organic transformations, while those from the 5d series (Os, Ir, Pt) are often viewed as more inert, while providing useful models for reactive complexes from the second row. In reality, there are many exceptions to this general perception, and many useful catalysts based on the heavier metals are known. This book is the first to provide comprehensive coverage of the application of one of these metals, iridium, in organic synthesis. An impressive list of authors has contributed 15 chapters that review progress across the full range of current research in this area.
机译:就基础研究和工业应用而言,铂族金属催化有机反应是现代化学的基石。在这些过渡金属中,通常认为4d系列的那些(Ru,Rh,Pd)是有机转化的活性更高的催化剂,而5d系列的那些(Os,Ir,Pt)通常被认为是惰性的,同时为第二行的反应性配合物提供有用的模型。实际上,对该一般认识有许多例外,并且已知许多基于重金属的有用催化剂。这本书是第一本全面介绍这些金属铱中的一种在有机合成中的应用的书。令人印象深刻的作者列表贡献了15章,回顾了该领域当前所有研究的进展。

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