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首页> 外文期刊>The European physical journal: Special topics >Theory of collective excitations in simple liquids
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Theory of collective excitations in simple liquids

机译:简单液体中的集体激发理论

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摘要

We present a parameter-free theory of the collective excitations in simple liquids such as liquid metals or rare gases. The theory is based on the mode-coupling theory (MCT), which has been previously applied successfully for explaining the liquid-to glass transition. The only input is the liquid structure factor. We achieve good agreement both for the liquid dispersion (maximum of the longitudinal current spectrum) and width (damping) with experimental findings. The time-dependent memory function predicted by MCT has a twostep exponential decay as previously found in computer simulations. Furthermore MCT predicts a scaling of the liquid dispersion with the effective hard-sphere diameter of the materials. This scaling is obeyed by the available experimental data.
机译:我们提出了一种简单的液体(例如液态金属或稀有气体)中集体激发的无参数理论。该理论基于模式耦合理论(MCT),该模式先前已成功用于解释液体到玻璃的转变。唯一的输入是液体结构因子。我们在液体分散度(最大纵向电流谱)和宽度(阻尼)方面均与实验结果达成了良好的协议。如先前在计算机仿真中发现的那样,MCT预测的随时间变化的记忆函数具有两步指数衰减。此外,MCT预测液体分散体随材料的有效硬球直径成比例变化。可用的实验数据将遵守这种缩放比例。

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