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Leaching of metals from fly ashes in the presence of complexing agents

机译:在络合剂存在下从飞灰中浸出金属

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摘要

The leachability of some metals (Al, As, Ba, Ca, Cr, Cu, Fe, K, Mg, Mn, Ti, Zn) from fly ashes was studied in the presence of ethylenedaimine tetraacetic acid (EDTA) and naturally occurring complexing agents-humic acid (HAs). Secondary complex- forming equilibria taking place in the leachates increase significantly the leached amounts of most metals. Kinetic experiment showed that almost the whole "available" amounts of metals are leached form fly ash within a time period of several hours (mostly within 20 h), with exceptions of matrix constituents (typically aluminium), which are released more slowly.
机译:在乙二胺四乙酸(EDTA)和天然存在的络合剂存在下,研究了一些金属(铝,砷,钡​​,钙,铬,铜,铁,钾,镁,锰,钛,锌)的可浸出性-腐植酸(HAs)。在渗滤液中发生的次级络合物形成平衡显着提高了大多数金属的浸出量。动力学实验表明,几乎所有“可用”量的金属都在数小时内(大部分在20小时内)从粉煤灰中浸出,但基质成分(通常是铝)的释放速度较慢。

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