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Modeling of mercury sorption by activated carbon in a confined, a semi-fluidized, and a fluidized bed

机译:在密闭,半流化和流化床中用活性炭吸附汞的模型

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摘要

A process model was developed to simulate elemental mercury sorption by activated carbon in three distinct beds, namely a confined, a semi-fluidized, and a fluidized bed. The model involved the coupling of a kinetic model based on the mechanisms of surface equilibrium and external mass transfer, and a material balance model base don the tank-in-series approach. For surface equilibrium, three different equilibrium laws were used in the model, namely the Henry's law, the Langmuir isotherm and the Fruendlich isotherm. Literature mercury sorption data were used to determine the best-fit values of parameters for these equili- Brium expressions.
机译:开发了一个过程模型来模拟活性炭在三个不同的床(即密闭床,半流化床和流化床)中对元素汞的吸附。该模型涉及基于表面平衡和外部传质机理的动力学模型的耦合,以及基于“串联罐”方法的材料平衡模型的耦合。对于表面平衡,模型中使用了三种不同的平衡定律,即亨利定律,朗缪尔等温线和Fruendlich等温线。文献中的汞吸附数据用于确定这些平衡表达式的参数的最佳拟合值。

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