Methane and carbon dioxide emission in a two-phase olive oil mill sludge windrow pile during composting

摘要

The aim of this work was to make some preliminary evaluations on CO_2 and CH_4 emissions during composting of two-phase olive oil mill sludge (OOMS). OOMS, olive tree leaves (OTL) and shredded olive tree branches (OTB) were used as feedstock for Pile Ⅰ and Pile Ⅱ with a 1:1:1 and 1:1:2 v/v ratio, respectively. Each pile was originally 1.2 m high, 2.0 m wide and approximately 15.0 m long. Four 500 ml volume glass funnels were inverted and introduced in each pile, two in the core (buried 50-60 cm from the surface) and two near the surface under a thin 10-15 cm layer of the mixture. Thin (0.5 cm diameter) plastic, 80 cm long tubes were connected to the funnels. A mobile gas analyser (GA2000) was used to measure the composition (by volume) of O_2, CO_2 and CH_4 on a daily basis. The funnels were removed prior to each turning and reinserted afterwards. From each pair of funnels (core and surface) of both piles, one was kept closed between samplings. Two way ANOVA was used to test differences between piles and among the tubes. Post hoc Tukey tests were also used to further investigate these differences. There was a significant difference (at p < 0.001) in the two piles for all three gases. The average concentrations of O_2, CO_2 and CH_4 in Pile Ⅰ, from all four funnels was 16.86%, 3.89% and 0.25%, respectively, where for Pile Ⅱ the average values were 18.07%, 2.38% and 0.04%, respectively. The presence of OOMS in larger amounts in Pile Ⅰ (resulting in more intense decomposing phenomena), and the larger particle size of OTB in Pile Ⅱ (resulting in increasing porosity) are the probable causes of these significant differences. Samples from open funnels presented lower, but not significantly lower, O_2 composition (higher for CO_2 and CH_4) in comparison with closed funnels in both depths and both piles. Not significant were also the different mean gas compositions between core and surface funnels in the same pile.