Distribution of recoverable metal resources and harmful elements depending on particle size and density in municipal solid waste incineration bottom ash from dry discharge system

摘要

Although municipal solid waste incineration bottom ash (BA) has the potential to be used as a metal resource, it raises concerns about the potential release of harmful elements into the environment. Element distribution in terms of particle size and density should be assessed to determine the fractions for the metal resources' recovery and to remove harmful elements. For this purpose, this study proposed a series of sorting processes based on the distribution of 25 elements in the sorted fractions by sieving, magnetic separation, air table sorting, and milling from dry BA < 8 mm. The Ca, Na, Mg, P, S, Cl, and Ti contents exhibited a decreasing tendency with increasing particle density and could affect the formation of low-density particles. The highest density fraction of non-magnetic components of 0.5-8 mm had abundant metal particles and recorded high Cu, Zn, Cr, Ni, Mo, Fe, Pb, Sb, and Au contents. In particular, the Cu (132000 mg-Cu/kg) and Zn (43000 mg-Zn/kg) contents demonstrated potential as metal resources. The fraction contained considerable proportions of Mo (77%), Cd (46%), Cu (39%), Zn (34%), Pb (26%), Au (40%), and Ag (18%) of the total amount. After milling and sieving of the highest density fraction, a substantial amount of Cd (44%), Cu (18%), Zn (12%), Pb (13%), and Ag (11%) were found in residual minerals; they could become harmful elements when recycled for construction purposes. The results show that air table sorting can separate metal resources and harmful elements before milling of BA.