Hydrogen production from food wastes and gas post-treatment by CO_2 adsorption

摘要

The production of H_2 by biological means, although still far from being a commercially viable proposition, offers great promise for the future. Purification of the biogas obtained may lead to the production of highly concentrated H_2 streams appropriate for industrial application. This research work evaluates the dark fermentation of food wastes and assesses the possibility of adsorbing CO_2 from the gas stream by means of a low cost biomass-based adsorbent. The reactor used was a completely stirred tank reactor run at different hydraulic retention times (HRTs) while the concentration of solids of the feeding stream was kept constant. The results obtained demonstrate that the H_2 yields from the fermentation of food wastes were affected by modifications in the hydraulic retention time (HRT) due to incomplete hydrolysis. The decrease in the duration of fermentation had a negative effect on the conversion of the substrate into soluble products. This resulted in a lower amount of soluble substrate being available for metabol-isation by H_2 producing microflora leading to a reduction in specific H_2 production. Adsorption of CO_2 from a gas stream generated from the dark fermentation process was successfully carried out. The data obtained demonstrate that the column filled with biomass-derived activated carbon resulted in a high degree of hydrogen purification. Co-adsorption of H_2S onto the activated carbon also took place, there being no evidence of H_2S present in the bio-H_2 exiting the column. Nevertheless, the concentration of H_2S was very low, and this co-adsorption did not affect the CO_2 capture capacity of the activated carbon.