Leaching characteristics of calcium-based compounds in MSWI Residues: From the viewpoint of clogging risk

摘要

Leachate collection system (LCS) clogging caused by calcium precipitation would be disadvantageous to landfill stability and operation. Meanwhile, calcium-based compounds are the main constituents in both municipal solid waste incineration bottom ash (MSWIBA) and stabilized air pollution control residues (SAPCR), which would increase the risk of LCS clogging once these calcium-rich residues were disposed in landfills. The leaching behaviors of calcium from the four compounds and municipal solid waste incineration (MSWI) residues were studied, and the influencing factors on leaching were discussed. The results showed that pH was the crucial factor in the calcium leaching process. CaCO_3 and CaSiO_3 began leaching when the leachate pH decreased to less than 7 and 10, respectively, while Ca_3(PO_4)_2 leached at pH ＜ 12. CaSO_4 could hardly dissolve in the experimental conditions. Moreover, the sequence of the leaching rate for the different calcium-based compounds is as follows: CaSiO_3 ＞ Ca_3(PO_4)_2 ＞ CaCO_3. The calcium leaching from the MSWIBA and SAPCR separately started from pH ＜ 7 and pH ＜ 12, resulting from CaCO_3 and Ca_3(PO_4)_2 leaching respectively, which was proven by the X-ray diffraction results. Based on the leaching characteristics of the different calcium compounds and the mineral phase of calcium in the incineration residues, simulated computation of their clogging potential was conducted, providing the theoretical basis for the risk assessment pertaining to LCS clogging in landfills.