Hydrothermal carbonization of different wetland biomass wastes: Phosphorus reclamation and hydrochar production

摘要

Hydrothermal carbonization (HTC) has drawn increasing interest for the disposal of solid wastes with a high moisture content, while minimal attention has been paid to HTC treatment of wetland plants and the corresponding phosphorus (P) transformation. In order to evaluate its feasibility for wetland plants treatment, hydrochars from different wetland plants were produced at different temperatures (200 ℃, 220 ℃, 240 ℃, and 260 ℃) and characterized, and the transformation of P was investigated. In comparison with wetland plant derived biochars, the derived hydrochars had a moderate pH (5.0-7.7), more oxygen-containing groups, and higher energy density (18.0-27.1 MJ kg~(-1)). These properties were affected by hydrothermal temperature and feedstock choice. In contrast to high water-soluble P in biomass (71.0-73.2% of total P), more recalcitrant P species formed in hydrochars, implying that HTC treatment could achieve P immobilization and reduce P leaching loss. Nuclear magnetic resonance (NMR) results indicated that monoester-P and soluble orthophosphate were transformed to insoluble orthophosphate during the HTC treatment. Therefore, HTC is a promising treatment technique for wetland plants to produce valuable char with P reclamation.