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Synthesis and characterization of sensible thermal heat storage mixture containing phosphate compound of cobalt and sodium

机译:含钴和钠的磷酸盐化合物的显热蓄热混合物的合成与表征

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The sensible thermal heat storage mixture containing hydrated cobalt phosphate, anhydrous disodium hydrogen phosphate and sodium sulfate has been synthesized and characterized with different measurement techniques. The specific heat capacity was measured using Differential Scanning Calorimetry (DSC) at heating rate of 10 and 15 K min(-1) in atmospheric O-2. Both calcined and non calcined mixture show endothermic behaviour. This endothermic behaviour of these mixtures shows their potential to be used as thermal heat storage material. The endothermic behaviour of calcined mixture and also certain paint is reduced by using this mixture with paint in less than 1%. So, this composite material can be used as heat dissipating material. The calculated refractive index of these mixtures is similar to 2.55. The calculated band gap of both calcined and non calcined mixtures is 2.35 eV.
机译:合成了含有水合磷酸钴,无水磷酸氢二钠和硫酸钠的显热储热混合物,并用不同的测量技术对其进行了表征。使用差示扫描量热法(DSC)在大气O-2中以10和15 K min(-1)的加热速率测量比热容。煅烧和未煅烧的混合物均显示出吸热行为。这些混合物的吸热行为表明它们有潜力用作储热材料。通过将该混合物与涂料一起使用小于1%,可以降低煅烧混合物以及某些涂料的吸热性能。因此,该复合材料可以用作散热材料。这些混合物的计算出的折射率类似于2.55。煅烧和非煅烧混合物的计算带隙为2.35eV。

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