Comment on 'Cycling Li-O-2 batteries via LiOH formation and decomposition'

摘要

Based on a simple thermodynamic analysis, we show that iodide-mediated electrochemical decomposition of lithium hydroxide (LiOH) likely occurs through a different mechanism than that proposed by Liu et al. (Research Article, 30 October 2015, p. 530). The mismatch in thermodynamic potentials for iodide/triiodide (I-/I-3(-)) redox and O-2 evolution from LiOH implies a different active iodine/oxygen electrochemistry on battery charge. It is therefore possible that the system described in Liu et al. may not form the basis for a rechargeable lithium-oxygen (Li-O-2) battery.