Luminescence properties and energy transfer investigations of Ce~(3+) singly doped and Ce~(3+)/Tb~(3+) codoped Na_3LuSi_2o_7 phosphors

摘要

The Na3LuSi2O7:Ce3+ and Na3LuSi2O7:Ce3+, Tb3+ phosphors were synthesized under a weak reducing atmosphere by the traditional high temperature solid state reaction method. The synthesized phosphors were characterized by X-ray diffraction (XRD), Photoluminescence (PL) emission and excitation spectra. The effects of Ce3+ singly doped and Ce3+/Tb3+ codoped concentrations on the structure, luminescence properties and energy transfer of Na3LuSi2O7 phosphors were studied in detail. The results indicated that the energy transfers between Ce3+ and Tb3+ in the host occurred mainly via a dipole-quadrupole mechanism, and the critical distances of the ion pairs (R-c) were calculated by the quenching concentration method and spectral overlap method. Based on the good PL properties adjusting the doping concentration of the activators (Ce3+,Tb3+) might be promising as a host material for solid-state lighting and display fields.