Hydrothermal synthesis, structural characterization and thermal, spectroscopic and magnetic properties of the inorganic-organic hybrid phosphate, [(C_2N_2H_9)VF(PO_4)]

摘要

The [(C_2N_2H_9)VF(PO_4)] compound has been synthesized by hydrothermal techniques under autogeneous pressure at 170℃. The compound was characterized from X-ray powder diffraction data with the Rietveld method. Its crystal structure consists of sheets linked by the ethylenediammonium cations and constructed by chains of VO_3F_2N octahedra. The thermal study indicates that the compound is stable up to 290℃. In the IR spectrum the bands of both the ethylenediammonium and phosphate ions are observed. From the reflectance diffuse spectrum the Dq and Racah parameters have been calculated. The magnetic measurements indicate the presence of antiferromagnetic interactions.